2-[(E)-(Dimethylamino)methyleneamino]benzonitrile
نویسندگان
چکیده
In the title compound, C(10)H(11)N(3), the amidine unit, including the two methyl substituents, is virtually planar [maximum deviation = 0.016 (5) Å]. The plane of the benzene ring forms a dihedral angle of 46.5 (3)° with the amidine group.
منابع مشابه
4-{2-[4-(Dimethylamino)phenyl]ethylidene}benzonitrile
In the crystal of the title compound, C(17)H(16)N(2), mol-ecules are linked by C-H⋯N hydrogen bonds, forming rings of graph-set motifs R(2) (1)(6) and R(2) (2)(10). The title mol-ecule is close to planar, with a dihedral angle between the aromatic rings of 0.6 (1)°. Torsion angles confirm a conformational trans structure.
متن کامل3-[4-(Dimethylamino)benzylideneamino]benzonitrile
The mol-ecule of the title Schiff base, C(16)H(15)N(3), is non-planar and displays a trans configuration with respect to the C=N double bond. The two benzene rings make a dihedral angle of 49.24 (3)°.
متن کامل(E)-4-[4-(Dimethylamino)benzylideneamino]benzonitrile
The mol-ecule of the title compound, C(16)H(15)N(3), displays a trans configuration with respect to the C=N double bond. The mol-ecule is not planar, the dihedral angle between the benzene rings being 57.83 (9)°. The crystal packing is stabilized only by van der Waals inter-actions.
متن کامل6-[(Dimethylamino)methyleneamino]-1,3-dimethylpyrimidine-2,4(1H,3H)-dione dihydrate
Uracil, the pyrimidine nucleobase, which combined with adenine forms one of the major motifs present in the biopolymer RNA, is also involved in the self-assembly of RNA. In the title compound, C(9)H(14)N(4)O(2)·2H(2)O, the asymmetric unit contains one dimethyl-amino-uracil group and two water mol-ecules. The plane of the N=C-NMe(2) side chain is inclined at 27.6 (5)° to the plane of the uracil ...
متن کامل3-[2-(4,4-Dimethyl-2,6-dioxocyclohexylidene)hydrazinyl]benzonitrile
The title compound, C(15)H(15)N(3)O(2), contains benzonitrile and 4,4-dimethyl-2,6-dioxocyclo-hexyl-idene groups connected via a hydrazinyl group. The structure is in the hydrazone tautomeric form in the solid state. The benzonitrile and hydrazinyl groups (3-hydrazinylbenzonitrile) are essentially coplanar with an r.m.s. deviation of 0.016 Å. Intra-molecular N-H⋯O hydrogen bonding helps to stab...
متن کامل